Introduction to the performance of SANY-1000 lithium adsorption resin
1. Scientific
Information of Lithium Adsorption Resin
A. Chemical Structure Resin and Specific Functional Groups (i.e: Sulphonates)
Molecular formula: Al(OH)3 nLiX mH2O
Aluminum hydroxide
lithium absorbent
B. Selectivity respect to sodium, potassium, magnesium, calcium, boron
Lithium absorbent
is selective and only absorbs lithium, which does not absorb other ions such as
the potassium, sodium, magnesium, calcium, boron, etc.
C. Mechanism of Lithium Adsorption on Resin and Mechanism of Chloride Co - Adsorption
“It is likely that lithium ion enters the inside of octahedral cavity inside the aluminum hydroxide layer in the form of bare ion, and to achieve the charge balance, chloride ion enters the interlayer. The difference between the sieve effect and the hydration of lithium ion to other ions is the main reason that the absorbent has a relatively good selectivity to the lithium.”
Quoted from
Journal of Salt Lake Research, Issue 3, 2018
2.Technical
Information of Lithium Adsorption Resin:
A. Physics
Characteristic of Resin
i. Particle size
0.3~1.5mm
ii. Porosity 45%
iii. Density
0.62g/cm3
B. Adsorption:
i. Specific
lithium adsorption capacity [milligram Li /gr resin]: 3~6 mg/g
ii. Specific
chloride adsorption capacity [milligram Li /gr resin]:15~30mg/g
iii. Specific
sodium, potassium, magnesium, calcium, boron adsorption capacity [milligram Li
/gr resin]: 0.1mg/g,no absorption of sodium, potassium, magnesium, calcium and boron
is found
C. Desorption:
i. Specific
lithium desorption capacity [milligram Li /gr resin]: 3~6 mg/g
ii. Specific
chloride desorption capacity [milligram Li /gr resin]: 15~30mg/g
iii. Specific
sodium, potassium, magnesium, calcium, boron desorption capacity [milligram Li
/gr resin]: 0.1mg/g, no absorption of sodium, potassium, magnesium, calcium and boron
is found
3. Overall
Process Flowsheet Operational Bases
To produce Lithium Carbonate
Raw ore
brine→absorption and extraction of lithium→analysis with fresh
water→concentration and refining with membrane method→forced concentration or
concentration in solar pond→secondary refining→addition of sodium carbonate to
produce lithium carbonate→separation and washing→drying, grinding and
packaging→lithium carbonate
4.Overall
Process Design Criteria
A. Natural Salt
Lake Brine Composition Range: Li [gpL]; Na [gpL]; K [gpL]; Mg [gpL]; B [gpL],
etc.
: Li 0.1~5g/L; Na
5~80g/L; K5~20g/L; Mg 5~120g/L; B 0.1~10g/L,
Lithium Recovery
[%]:≥80%(综合收率)(comprehensive
recovery rate)
B. Specific Resin
Consumption [kg Resin/Ton LCE]
10~20Kg Resin/Ton
LCE
C. Specific Water [M3
/Ton LCE]:
60~200 M 3 /Ton
LCE
D. Specific Energy
Consumption [KWh/Ton LCE]:
2000~5500KWh/Ton
LCE
E. Human Resources
[HH/Ton LCE]
9~15HH/Ton LCE
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